Practice Test


Q1) Which of the following is not an organic compound? Show Answer


Q2) The first organic compound ever prepared in laboratory from elements is Show Answer


Q3) Compounds having the same molecular formula but differing in their structure are called as Show Answer


Q4) The ability of carbon atom to combine with one another to form long chains, branched chains and rings is known as Show Answer


Q5) Fuel used in automobiles is a mixture of Show Answer


Q6) Which of the following is not a petroleum product? Show Answer


Q7) Common element in all the organic compounds other than hydrogen is Show Answer


Q8) Which of the following statements is wrong? Show Answer


Q9) Which of the following elements forms the largest number of compounds? Show Answer


Q10) Which of the following is not the criteria for purity of a substance? Show Answer


Q11) Sugar is obtained from its saturated solution by Show Answer


Q12) Benzoic acid can be purified by Show Answer


Q13) Organic liquids like acetone is purified by _____ methods. Show Answer


Q14) Extraction of oils and fats from seeds and essence from flowers is done by using Show Answer


Q15) To purify mixtures of organic compounds _____ method is used. Show Answer


Q16) Sodium chloride crystals are Show Answer


Q17) Alum crystals are Show Answer


Q18) Copper sulphate crystals are Show Answer


Q19) Quartz crystals are Show Answer


Q20) The process of obtaining a solid in a pure crystalline form, from solution is known as Show Answer


Q21) The process ______ is used to separate two or more solids which are soluble in a given solvent Show Answer


Q22) Urea melts at _____ and acetanilide melts at 387 K. Show Answer


Q23) The soluble solids and miscible liquids are separated by Show Answer


Q24) Process used for the separation of compounds from the mixture of two or more miscible liquids having different boiling points is called Show Answer


Q25) Separation of binary mixture of acetone and benzene is done by various types of Show Answer


Q26) The purity of crystals can be checked by determining its Show Answer


Q27) A crystalline substance is that Show Answer


Q28) Boiling point of a liquid depends upon Show Answer


Q29) In the detection of melting point, thermometer along with the capillary containing the substance is placed in Show Answer


Q30) When undissolved solid is in contact with its solution, the supernatant liquid is called Show Answer


Q31) To determine the melting point, powdered substance is filled in Show Answer


Q32) To determine the boiling point, powdered liquid is filled in Show Answer


Q33) The two solids of variable solubilities are separated by the process of Show Answer


Q34) In Lassaigne method, the elements of the organic compound are fused with metallic Show Answer


Q35) The presence of nitrogen in an organic compound is confirmed when the complex form has Show Answer


Q36) The formation of ______ precipitate which is insoluble in ammonium hydroxide confirms the presence of iodine Show Answer


Q37) In Lassaigne method, the treatment of sodium fusion extract with sodium niroprusside produces violet colour which indicates the presence of Show Answer


Q38) _____ is usually detected from the chemical properties of the compound Show Answer


Q39) ______ method is not applicable to compounds containing nitrogen in the form of nitro and azo group Show Answer


Q40) Carius method is used for the estimation of fluorine as ______ is water soluble. Show Answer


Q41) In the Kjeldahls method, nitrogen in the organic compound is converted to Show Answer


Q42) 0.4 gm of an organic compound gave 0.188 g of silver bromide by halogen estimation method. The percentage of bromine in the compound is(At. Mass of Ag = 108, Br = 80) Show Answer


Q43) In the Dumas method, for the estimation of nitrogen, 0.84 g of an organic compound gave 448 mL of nitrogen at S.T.P. The percentage of nitrogen in the compound is Show Answer


Q44) 0.2585 g of an organic compound containing iodine was heated with excess of strong nitric acid and silver nitrate in a Carius tube. The precipitate of silver iodide was filtered, washed and dried. Its weight was found to be 0.3894 g. Calculate the percentage of iodine in the compound Show Answer


Q45) 0.4 g of an organic compound containing phosphorus gave 0.555 g of magnesium pyrophosphate by usual analysis. Calulate the percentage of phosphorus in the compound Show Answer


Q46) Dumas method is used for estimation of Show Answer


Q47) ______ has a linear structure due to sp hybridization of carbon Show Answer


Q48) Bond enthalpy and bond length in organic compounds are influenced by Show Answer


Q49) Aromatic compounds contain atleast one aromatic ring which resembles________ in their chemical behaviour Show Answer


Q50) The chemical properties of an organic compound are characterizes by its Show Answer


Q51) The homologous series consist of homologues which are arranged in the increasing order of their Show Answer


Q52) Which of the following is not a cyclic compound? Show Answer


Q53) Which of the following names is not correct in the IUPAC system of nomenclature? Show Answer


Q54) The compound having one isopropyl group is Show Answer


Q55) Which one of the following is not an alcohol? Show Answer


Q56) Which of the following compounds does not contain a C = O bond? Show Answer


Q57) The effect in which the displacements of electrons are temporary is called Show Answer


Q58) The phenomenon in which none of the structure describes most of the properties of the compound is termed as Show Answer


Q59) The number of contributing resonance structure contributes to Show Answer


Q60) In the '' no bond'' resonance structures carbon - carbon bond has _____ character Show Answer


Q61) Isopropyl radical has ______ hyperconjugation structures. Show Answer


Q62) The process of breaking or cleavage of covalent bond is known as Show Answer


Q63) Homolysis also occurs in the presence of catalyst such as Show Answer


Q64) The species in which carbon atom possesses a octet of electrons and a negative charge is called Show Answer


Q65) Stability of carbocation increases as the number of _____ substituents bonded to positively charged carbon atom increases Show Answer


Q66) Carbocations are______ and acts as a ______ Show Answer


Q67) Addition reaction is not shown by Show Answer


Q68) Which of the following is an example of elimination reaction? Show Answer


Q69) Purification of aniline and nitrobenzene can be done by ______ method Show Answer


Q70) Monoclinic sulphur has _______ crystals Show Answer


Q71) Copper sulphate crystal are of ______ colour Show Answer


Q72) Non - volatile soluble Impurities can be removed from a liquid by the process of Show Answer


Q73) The smallest ratio which shows the number of atoms of each element in a molecule of a compound is the Show Answer


Q74) In Lassaigne method, the presence of ______ is confirmed, if the white precipitate is soluble in ammonium hydroxide Show Answer


Q75) Homologues differ in molecular weight by Show Answer


Q76) Identify the bond formed which is polar in nature Show Answer


Q77) Which of the following carbocation has the least stability? Show Answer


Q78) The free radicals resulting from the cleavage of a bond are Show Answer


Q79) The general formula for an ether is
Show Answer


Q80) The general formula of a carboxylic acid is
Show Answer


Q81) The general formula of an ester is
Show Answer


Q82) ______ is filled in U-tube to absorb water from the organic mixture Show Answer


Q83) Molecular formula of benzene is Show Answer


Q84) In the Dumas method for the estimation of nitrogen, the gas collected in nitrometer is Show Answer


Q85) An organic compound containing bromine gave the following result on analysis C = 21.96 %, H = 4.58 % and Br = 73.36 % Find the molecular formula of the compound if the vapour density is 54.5 Show Answer


Q86) An organic substance on combusion gave 53.2% carbon, 15.5% hydrogen and 31.3% nitrogen. If the molecular weight is 45. Find the molecular formula Show Answer


Q87) The angle between the four valencies of carbon is Show Answer


Q88) In the homologous series, the successive members differ from each other in molecular formula by Show Answer


Q89) Which of the following is methanol? Show Answer


Q90) Which of the following is butan - 2 -ol? Show Answer


Q91) Which one of the following could be a cyclic alkane? Show Answer


Q92) Identify the electron withdrawing group from the following Show Answer


Q93) Which of the following carbocation wil be the most stable? Show Answer


Q94) Which of the following species does not act as a nucleophile? Show Answer


Q95) Identify the molecule which is NOT a nucleophile from the following Show Answer


Q96) Which of the following series contains only nucleophiles? Show Answer


Q97) Which of the following species has electron releasing (or + I inductive) effect? Show Answer


Q98) Which of the following species is not an electrophile? Show Answer


Q99) Which of the following is an electrophile? Show Answer


Q100) Friedrich wohler synthesized urea by heating a mixture of Show Answer


Q101) An organic compound containing C, H and N give the following result on analysis
C = 40%, H = 13.33% and N = 46.67% what would be the empirical formula? Show Answer


Q102) Which is the structural formula for 3 - ethyl, 2 - methylhex - 1 -ene? Show Answer


Q103) Which is the structural formula of 1, 2, 3 - propanetriol? Show Answer


Q104) The name of some compounds are given, which one is not in IUPAC system? Show Answer


Q105) Which is 1, 1- dimethylcyclohexane? Show Answer


Q106) Which is 1, 2- dimethylcyclobutane? Show Answer


Q107) Which of the following is hexan - 2 - ol ? Show Answer


Q108) Which of the following is 4-methylpentan-2-ol ? Show Answer


Q109) Which of the following is 2-methylpentan-3-ol? Show Answer


Q110) Which of the following is 4-methylpentan-1-ol ? Show Answer


Q111) Which of the following is a cycloalkane ? Show Answer


Q112) Which is 1, 1-Dichlorobutane ? Show Answer


Q113) Which structure below represents a ketone ? Show Answer


Q114) Which structure below represents an aldehyde ? Show Answer


Q115) Which structure below represents an ether ? Show Answer


Q116) The general formula of an aldehyde is Show Answer


Q117) The structure of 4 methyl - 2 - penten - 1 - ol is Show Answer


Q118) Iso-butyl chloride is Show Answer


Q119) 2-Methyl-2-butene will be represented as Show Answer


Q120) Which class of compound is not reported in IUPAC nomenclature? Show Answer


Q121) Cyclohexane is Show Answer


Q122) The structure representing a heterocyclic compound is Show Answer


Q123) The formula of 3-chloro-2,2dimethylbutane is Show Answer


Q124) 3-Methylpenta-1,3-diene is Show Answer


Q125) Which is an alternate name for methyl-n-propylmethane? Show Answer


Q126) Which of the following is heterocyclic aromatic species? Show Answer


Q127) Which nomenclature in IUPAC is not correct? Show Answer


Q128) 3-penylpropenoic acid is IUPAC name of Show Answer


Q129) Which among the following is the correct IUPAC name of isomylene? Show Answer


Q130) The correct IUPAC name of acetonitrile is Show Answer


Q131) neo-Heptyl alcohol is correctly represented as Show Answer


Q132) A student named the compound as 1,4-butadiene Show Answer


Q133) 2-Methylbut-2ene will be represented as Show Answer


Q134) The incorrect IUPAC name is Show Answer


Q135) IUPAC name of 3-iso-propyl-o-xylene is Show Answer


Q136) IUPAC name of 4-iso-propyl-m-xylene is Show Answer


Q137) Names of some compound are given. Which one is not in IUPAC system? Show Answer


Q138) Which of the following IUPAC names is correct? Show Answer


Q139) The structural formula of 2-methyl-2-butene is Show Answer


Q140) vinyl carbinol is Show Answer


Q141) The correct IUPAC name of phenetole is Show Answer


Q142) The IUPAC name of acraldehyde is Show Answer


Q143) The structural formula of cyclohexyl alcohol is Show Answer


Q144) The IUPAC name of tert-butyl chloride is Show Answer


Q145) Indicate the wrongly named compound Show Answer


Q146) Which of the following compound has wrong IUPAC name? Show Answer


Q147) The compound which has one iso-propyl group is Show Answer


Q148) Ammonia molecule is Show Answer


Q149) Heterolysis of propane gives Show Answer


Q150) Which of the following contains only three pairs of electrons Show Answer


Q151) Which of the following species is paramagnetic? Show Answer


Q152) Electrophiles are Show Answer


Q153) Homolytic and heterolytic bond dissociation eneriges are Show Answer


Q154) In hyperconjugation, the atom involved is Show Answer


Q155) Hyperconjugation is Show Answer


Q156) Reaction involving heterolytic fission are said to be produce via Show Answer


Q157) Due to its sextet (having six electrons), the carbonium ions are Show Answer


Q158) The +I-effect (inductive effect) is shown by Show Answer


Q159) Which of the following is singlet carbene? Show Answer


Q160) Which one of the following compound is most acidic? Show Answer


Q161) The -I effect is shown by Show Answer


Q162) Which of the following is strong base? Show Answer


Q163) Which of the following is an electrophilic reagent? Show Answer


Q164) Shifting of electron of a multiple bond under the influence of a reagent is called Show Answer


Q165) An alkene is most likely to react with Show Answer


Q166) Sulphur trioxide is Show Answer


Q167) Homolytic fission of C - C bond in ethane gives an intermediate in which carbon is ................ hybridised. Show Answer


Q168) In carbonium ion the carbon bearing the positive charge is Show Answer


Q169) The central C atom of a carbanion possesses Show Answer


Q170) Chlorine in vinyl chloride is less reactive because Show Answer


Q171) The shape of carbonium ion is Show Answer


Q172) Which of the following is nucleophile? Show Answer


Q173) A neutral divalent carbon intermediate produced by the removal of two attached atom is called Show Answer


Q174) Which group has the maximum inductive effect? Show Answer


Q175) Zero inductive effect is shown by Show Answer


Q176) The structure of tertiary butyl carbonium ion is Show Answer


Q177) The compound which gives the most stable carbonium ion on dehydration is Show Answer


Q178) Which of the following statement is not correct? Show Answer


Q179) Which one of the following does not show resonance? Show Answer


Q180) Select the correct order of basic nature Show Answer


Q181) Which of the following can act as an nucleophile? Show Answer


Q182) The strongest base among the following Show Answer


Q183) Free radical can undergo Show Answer


Q184) The homolytic fission of a hydrocarbon results in the formation of Show Answer


Q185) Which of the following is not a nuclephile? Show Answer


Q186) Electrophilic reagent are Show Answer


Q187) Which of the following statement is false about resonance contribution structures? Show Answer


Q188) Which of the following is an electrophilic reagent? Show Answer


Q189) Heterolytic cleavage of a covalent bond gives only Show Answer


Q190) Which of the following is correct regarding the -I effect of the substituents? Show Answer


Q191) Nucleophilicity order is correctly represented by Show Answer


Q192) Which of the following is an electrophile? Show Answer


Q193) Which of the following is an nucleophile? Show Answer


Q194) The most reactive nucleophile among the following is Show Answer


Q195) Which of the following is most stable? Show Answer


Q196) Which of the following contains three pairs of electrons in the valence shell? Show Answer


Q197) Which of the following is the most stable carbocation (carbonium ion)? Show Answer


Q198) Which of the following is least stable? Show Answer


Q199) In which of the following homolytic bond fission takes place? Show Answer


Q200) Select the most stable carbocation from among the following. Show Answer


Q201) The compound having only primary hydrogen atom is Show Answer


Q202) Which of the following statement regarding the resonance energy of benzene is correct? Show Answer


Q203) The most stable carbonium ion among the following is Show Answer


Q204) Which of the following is least stable carbonium ion? Show Answer


Q205) Which of the following behaves both as a nucleophile and as an electrophile? Show Answer


Q206) Point out the correct statement about resonance? Show Answer


Q207) The most stable carbanion among the following is Show Answer


Q208) Resonance structure of a molecule does not have Show Answer


Q209) Which of the following acids would you expect to be the strongest? Show Answer


Q210) Among the following the most basic compound is Show Answer


Q211) Homolytic fission of C - C bond in ethane gives an intermediate in which carbon? Show Answer


Q212) The kind of delocalisation involving sigma bond orbitals is called Show Answer


Q213) The most unlikely representation of resonance structure of p-nitrophenoxide ion is Show Answer


Q214) Which of the following has the highest nucleophilicity? Show Answer


Q215) Which is most stable? Show Answer


Q216) The addition of HBr on 2-Butene is an example of Show Answer


Q217) Carbanions initiate Show Answer


Q218) Ease of abstraction of hydrogen is greater when attached to Show Answer


Q219) Why is light necessary to bring in chlorination reaction of alkane? Show Answer


Q220) What information is provided by reaction mechanism? Show Answer


Q221) Which of the following alkyl halides is used as a methylating agent? Show Answer


Q222) The reagent used in dehydrohalogenation process is Show Answer


Q223) Which one is an elimination reaction? Show Answer


Q224) The yield in organic reaction is generally poor because the reaction are Show Answer


Q225) The attacking species in the aromatic sulphonation is Show Answer


Q226) Addition of HI on double bond of propene yields iso-propyl iodide as major product. It is because the addition proceeds through Show Answer


Q227) Among the following compound which is most reactive towards nitration Show Answer


Q228) Dehydrogenation of ethanol to give ethanal is Show Answer


Q229) Acetaldehyde is the rearrangement product of Show Answer


Q230) Which of the following is an example of elimination reaction? Show Answer


Q231) Which species represent the electrophile in aromatic nitration? Show Answer


Q232) Which species represent the electrophile in aromatic nitration? Show Answer


Q233) The typical reaction of olefinic bond is Show Answer


Q234) The formation of cyanohydrin from a ketone is an example of Show Answer


Q235) The compound which gives least stable carbocation during dehydration is Show Answer


Q236) Which of the following is an example of nucleophile? Show Answer


Q237) Which of the following is non aromatic? Show Answer


Q238) The +I effect of alkyl group is in the order Show Answer


Q239) With a change in hybridisation of the carbon bearing the charge, the stability of a carbanion increase in the order Show Answer


Q240) Among the following, the least stable resonance structure is Show Answer


Q241) The IUPAC name of neo-pentane is Show Answer


Q242) 3-phenylpropenoic acid is IUPAC name of : Show Answer


Q243) The strain in bonds of cyclopropane is : Show Answer


Q244) Chlorine in vinyl chloride is less reactive because : Show Answer


Q245) The alkene that exhibits geometrical isomerism is Show Answer


Q246) Pick out the alkane which differs from the other members of the group Show Answer


Q247) Detection of sulphur in sodium extract is done by Show Answer


Q248) Acidified sodium fusion extract on addition of ferric chloride solution gives blood red colouration which
confirm the presence of Show Answer


Q249) Conversion of chlorobenzene to phenol involves Show Answer


Q250) In sulphur detection of an organic compound, sodium nitroprusside solution is added to sodium extract.
Formation of violet colour is due to Show Answer


Q251) The maximum bond energy is present Show Answer


Q252) The number of secondary hydrogens in 2, 2-dimethyl butane is Show Answer


Q253) Find the non-staggered form (s) of ethane : Show Answer


Q254) With a change in hybridisation of the carbon bearing the charge, the stability of a carbanion increase in the
order Show Answer


Q255) The addition reaction among the following is Show Answer


Q256) The correct definition for organic chemistry is : Show Answer


Q257) Which of the organic compounds will give red colour in Lassaigne test? Show Answer


Q258) The compound formed in the positive test for nitrogen with the Lassaigne solution of an organic
compound is Show Answer


Q259) The production of an optically active compound from a symmetric molecule without resolution is called : Show Answer


Q260) Which is wrong IUPAC name? Show Answer


Q261) Which of the following statements is wrong? Show Answer


Q262) Nitroethane can exhibit one of the following kind of isomerism Show Answer


Q263) Which of the following would show configurational enantiomorphism? Show Answer


Q264) Heterolysis of carbon-chlorine bond produces : Show Answer


Q265) Maximum enol content is in Show Answer


Q266) Which of the following compounds will show metamerism? Show Answer


Q267) Which of the following is elimination reaction Show Answer


Q268) Mixture of sugar and common salt is separated by crystallisation by dissolving in Show Answer


Q269) The general formula for cycloalkanes is : Show Answer


Q270) The bond that undergoes heterolytic cleavage most easily is Show Answer


Q271) Phosphorus is estimated as Show Answer


Q272) Species containing carbon with three bonds and an electron are called : Show Answer


Q273) Which of the aldehyde is most reactive? Show Answer


Q274) 3-methyl penta-1,3-diene is : Show Answer


Q275) Which of the following compounds is optically active? Show Answer


Q276) “The negative part of the addendum adds on the carbon atom joined to the least number of hydrogen
atoms.” This statement is called : Show Answer


Q277) d-tartaric acid and l-tartaric acid are : Show Answer


Q278) Which of the following is a pair of functional isomers? Show Answer


Q279) Which of the following is an optically active compound? Show Answer


Q280) Bond energy ……..with the increase in number of lone pairs on the bonded atoms. Show Answer


Q281) A liquid decomposes at its normal boiling point. It can be purified by Show Answer


Q282) On monochlorination of 2-methyl butane, the number of chiral compounds formed are : Show Answer


Q283) Stability of which intermediate is not governed by hyperconjugation? Show Answer


Q284) The ammonia evolved from the treatment of 0.30g of an organic compound for the estimation of nitrogen
was passed in 100mL of 0.1M sulphuric acid. The excess of acid required 20mL of 0.5 M sodium hydroxide
solution for complete neutralisation. The organic compound is Show Answer


Q285) Number of possible isomers of glucose are : Show Answer


Q286) The stability of 2,3-dimethyl but-2-ene is more than 2-butene. This can be explained in terms of : Show Answer


Q287) Protin solvent is Show Answer


Q288) Among the following compounds (I-III) the correct order of reaction with electrophilic reagand is Show Answer


Q289) How many chiral compounds are possible on monochlorination of 2-methyl butane? Show Answer


Q290) The epoxide ring consists of which of the following? Show Answer


Q291) The reaction which is not the example of nucleophilic substitution among the following is Show Answer


Q292) An important chemical method to resolve a racemic mixture makes use of the formation of : Show Answer


Q293) Which of the following complex formation indicates presence of sulphur in the organic compound when
sodium nitroprusside is added to sodium extract of the compound? Show Answer


Q294) Who pointed out the concept hyperconjugation? Show Answer


Q295) Alkyl halide can be converted into alkene by Show Answer


Q296) The optically active alkane with lowest molecular weight is : Show Answer


Q297) Which type of isomerism is most common among ethers? Show Answer


Q298) With a change in hybridisation of the carbon bearing the charge, the stability of a carbanion increase in the
order Show Answer


Q299) Which of the following compounds are not arranged on order of decreasing reactivity towards
electrophilic substitution? Show Answer


Q300) A mixture of camphor and benzoic acid can be separated by Show Answer


Q301) Resonance energy is more for Show Answer


Q302) Grignard reagent adds to Show Answer


Q303) Which of the following is not chiral? Show Answer


Q304) Detection of phosphorus in the compound can be done by its conversion into phosphate. Reagent to
identify phosphate ion is Show Answer


Q305) The hemolytic fission of a hydrocarbon results in the formation of: Show Answer


Q306) Methoxy methane and ethanol are Show Answer


Q307) Which one of the following monoenes does not exhibit geometric isomerism? Show Answer


Q308) When two halogen atoms are attached to two adjacent carbon atoms, the dihaloalkane is called : Show Answer


Q309) The electrophile involved in the sulphonation of benzene is Show Answer


Q310) In Kjeldahl’s method, then nitrogen present in the organic compound is quantitatively converted into Show Answer


Q311) The compound which gives the most stable carbonium ion on dehydration is Show Answer


Q312) A similarity between optical and geometrical isomerism is that : Show Answer


Q313) Reaction of phenol with chloroforms/sodium hydroxide to give o-hydroxy benzaldehyde involves the
formation of Show Answer


Q314) Which kind of fission is favoured by sunlight? Show Answer


Q315) Which class of compounds can exhibit geometrical isomerism? Show Answer


Q316) Which of the following compounds is optically active? Show Answer


Q317) To which ring size cycloalkanes, Baeyer’s strain theory is not valid? Show Answer


Q318) Which of the following orders is not correct regarding the – I effect of the substitutents? Show Answer


Q319) Lactic acid shows optical activity in : Show Answer


Q320) In cyclopropane, cyclobutane and cyclohexane, the common group is Show Answer


Q321) Allyl isocyanide has : Show Answer


Q322) +I effect is shown by Show Answer


Q323) Which one of the following is the stable structure of cyclohexatriene? Show Answer


Q324) Total number of rotational conformers of n-butane are : Show Answer


Q325) Sublimation is a process in which a solid Show Answer


Q326) The group named as benzal possesses ……nature. Show Answer


Q327) 29.5 mg of organic compound containing nitrogen was digested according to Kjeldahl’s method and the
evolved ammonia was absorbed in 20mL of 0.1 M HCl solution. The excess of the acid required 15mL of
0.1M NaOH solution for complete neutralisation. The percentage of nitrogen in the compound is Show Answer


Q328) The highest electrical conductivity of the following aqueous solutions is of Show Answer


Q329) Nucleophiles are : Show Answer


Q330) Ethyl acetoacetate exhibits : Show Answer


Q331) A molecule of urea can show Show Answer


Q332) Geometrical isomerism is possible in case of Show Answer


Q333) Anti-Markownikoff addition of HBr is not observed in : Show Answer


Q334) The number of 1°, 2° and 3° carbon atoms present in isopentane are respectively : Show Answer


Q335) The restricted rotation about carbon-carbon double bond in 2-butene is due to: Show Answer


Q336) Formation of acetylene from ethylene is an example of Show Answer


Q337) The structure of cis-bis (propenyl) ethane is : Show Answer


Q338) The compound which reacts with HBr obeying Markownikoff’s rule is: Show Answer


Q339) A molecule of benzene contains : Show Answer


Q340) Zn—Cu couple used as reducing agent is : Show Answer


Q341) Considering the state of hybridization of carbon atoms, find out the molecule among the following which is
linear? Show Answer


Q342) Tautomerism is not exhibited by Show Answer


Q343) Which of the substance is purified by sublimation? Show Answer


Q344) The number of optical enantiomorphs of tartaric acid : Show Answer


Q345) Which of the following is useful for making pure water from a solution of salt in water? Show Answer


Q346) Which of the following does not contain chiral carbon atom? Show Answer


Q347) Among the following orbital bonds, the angle is minimum between : Show Answer


Q348) Polarization of electron in acrolein may be written as Show Answer


Q349) Two crystalline forms of a substance, one being a mirror image of the other are called : Show Answer


Q350) Hyperconjugation is Show Answer


Q351) Which one of the following reactions is a condensation reaction? Show Answer


Q352) Which group has the maximum-Inductive effect? Show Answer


Q353) Which is incorrect about enantiomorphs? Show Answer


Q354) Which one is the seniormost functional group in the nomenclature of an organic compound if it possesses
more than one functional group? Show Answer


Q355) The reaction intermediate produced, by homolytic cleavage of a bond is called Show Answer


Q356) Fractional distillation is useful in distillation of Show Answer


Q357) Which of the following species is paramagnetic? Show Answer


Q358) Free radical has unpaired electron. Show Answer


Q359) Select the organic compound which was prepared for the first time in laboratory from its elements : Show Answer


Q360) Which of the following compounds can exist in optically active form? Show Answer


Q361) Select the most reactive cycloalkane : Show Answer


Q362) Glyoxal is Show Answer


Q363) IUPAC name of acraldehyde is Show Answer


Q364) What information is provided by reaction mechanism? Show Answer


Q365) The enolic from of acetone contains Show Answer


Q366) Which of the following acids has the smallest dissociation constant? Show Answer


Q367) Among the following the strongest nucleophile is Show Answer


Q368) Which of the following statements is correct? Show Answer


Q369) Which of the following species does not exert a resonance effect? Show Answer


Q370) Lactic acid molecule has Show Answer


Q371) The arrangement of atoms that characterises a particular stereoisomer is called : Show Answer


Q372) An alkane forms isomers if the number of carbon atoms is : Show Answer


Q373) Which of the following statements is correct? Show Answer


Q374) Qualitative test of halogens in an organic compound is made by Show Answer


Q375) Which one of the following will most readily be dehydrated in acidic conditions? Show Answer


Q376) The family to which methoxyethene belongs, is : Show Answer


Q377) Electrophiles are : Show Answer


Q378) Iso-propyl chloride undergoes hydrolysis by Show Answer


Q379) Carbon and hydrogen are estimated in organic compounds by Show Answer


Q380) The compound having highest dipole moment is : Show Answer


Q381) A free radical is : Show Answer


Q382) In electrophilic aromatic substitution reaction, the nitro group is meta directing because it Show Answer


Q383) Which of the following conformers for ethylene glycol is most stable? Show Answer


Q384) Which of the following compounds is resistant to nucleophilic attack by hydroxy ion? Show Answer


Q385) The stabilization due to resonance is maximum in : Show Answer


Q386) A mixture of camphor and benzoic acid can be easily separated by Show Answer


Q387) Fractional crystallisations is carried out to separate a mixture of Show Answer


Q388) The type of isomerism observed in urea molecule is : Show Answer


Q389) Which of the following intermediate have the complete octet around the carbon atom? Show Answer


Q390) A neutral divalent carbon intermediate produced by the removal of two attached atoms is called : Show Answer


Q391) Which types of isomerism is shown by 2, 3-dichlorobutane? Show Answer


Q392) Among the following compounds, the most acidic is Show Answer


Q393) Electrophiles are : Show Answer


Q394) On monochlorination of n-pentane, the number of isomers formed is : Show Answer


Q395) Cyclohexane is : Show Answer


Q396) Which of the following is a primary halide? Show Answer


Q397) The percentage of ′s′ character of the hybrid orbital of carbon in ethane, ethane and ethyne respectively
are : Show Answer


Q398) Which is a chiral molecule? Show Answer


Q399) The stability of a carbonium ion depends upon Show Answer


Q400) Bromination of alkanes involves Show Answer


Q401) The isomeric cis-2-butene and trans-2-butene can be distinguished on the basis of : Show Answer


Q402) Lassaigne’s test is not used for the detection of Show Answer


Q403) The simplest formula of a compound containing 50% of element X (at. wt 10) and 50% of element Y (at.
wt. 20) is Show Answer


Q404) n-pentane, iso-pentane, and neo – pentane are examples for isomers of the type Show Answer


Q405) Homolytic fission of C— C bond in ethane gives an intermediate in which carbon is ….hybridized. Show Answer


Q406) Pick out the correct statement from the following and choose the correct answer from the codes given
below
I. Hexa-1, 5-diene is a conjugated diene
II. Prop-1, 2-diene is conjugated diene
III. Hexa-1, 3-diene is a conjugated diene
IV. Buta-1, 3-diene is an isolated diene
V. Prop-1, 2-diene is a cumulative diene Show Answer


Q407) Which among the following is the correct IUPAC name of isoamylene? Show Answer


Q408) Which of the following compounds exhibits geometrical isomerism? Show Answer


Q409) Which one of the following compounds, is most acidic? Show Answer


Q410) An organic compound has carbon and hydrogen percentage in the ratio 6:1 and carbon and oxygen
percentages in the ratio 3:4. The compound has the empirical formula Show Answer


Q411) Among the following the one which does not exhibit functional group isomerism is : Show Answer


Q412) Which one of the following is a secondary alcohol? Show Answer


Q413) Electromeric effect is Show Answer


Q414) The angle of rotation of plane of polarized light depends upon : Show Answer


Q415) Which of the following shows geometrical isomerism? Show Answer


Q416) Which of the following cannot undergo nucleophilic substitution under ordinary conditions? Show Answer


Q417) The C— C bond length of the following molecules is in the order. Show Answer


Q418) Isomerism among compounds due to the migration of a proton is known as : Show Answer


Q419) Removal of hydrogen atom is easier when it is attached to : Show Answer


Q420) The order of stability of carbanions is : Show Answer


Q421) Glycerine contains Show Answer


Q422) Which of the following pairs of carbon skeletons in an example of isomerism? Show Answer


Q423) In the following the most stable conformation of n-butane is : Show Answer


Q424) An electrophilic reagent must have Show Answer


Q425) Which one of the starred carbons is the asymmetric one? Show Answer


Q426) The chemical name of anisole is Show Answer


Q427) How many optically active stereomers are possible for butan-2, 3-diol? Show Answer


Q428) Naphthalene molecule contains : Show Answer


Q429) The first organic compound urea was synthesized in the laboratory by: Show Answer


Q430) Which of the following is not a nucleophile? Show Answer


Q431) Which of the following compounds can exhibit optical isomerism? Show Answer


Q432) Which is the most stable carbocation? Show Answer


Q433) The correct structure of 4-bromo-3-methyl-but-1-ene. Show Answer


Q434) Which method is used to separate sugars? Show Answer


Q435) Sublimation can't be used for purification of Show Answer


Q436) Which of the following is phenyl ethanoate? Show Answer


Q437) Zero inductive effect is shown by : Show Answer


Q438) Which of the following alkyl halides is used as a methylating agent? Show Answer


Q439) Which one of the following has the most nucleophilic nitrogen? Show Answer


Q440) Chlorobenzene is 0, p-directing in electrophilic substituting reaction. The directing influence is explained
by Show Answer


Q441) Which of the following orders regarding relative stability of free radicals is correct? Show Answer


Q442) Carbon tetrachloride has no net dipole moment because of : Show Answer


Q443) The isomers which are interconverted through rotation around a single bond are Show Answer


Q444) The number of optical isomers of pent-3-en-2-ol is : Show Answer


Q445) Dehydrohalogenation of an alkyl halide is a/an Show Answer


Q446) The minimum number of carbon atoms which a ketone may contain is : Show Answer


Q447) What is the formula of tertiary butyl alcohol? Show Answer


Q448) The IUPAC name of neopentane is Show Answer


Q449) Select the strongest bond : Show Answer


Q450) Which of the following molecules is achiral? Show Answer


Q451) An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral carbon. The
ester formed will be Show Answer


Q452) Which of the following statements is necessarily true in the case of isomeric organic compounds? Show Answer


Q453) Cis - trans, isomers generally Show Answer


Q454) Among the following compounds nitrobenzene, benzene, aniline and phenol, the strongest basic behaviour
in acid medium is exhibited by : Show Answer


Q455) Geometrical isomerism is not shown by : Show Answer


Q456) An optically active compound is : Show Answer


Q457) In Lassaigen's test, the organic compound is fused with a piece of sodium metal in order to Show Answer


Q458) Which of the following sodium compound/compounds are formed when an organic compound containing
both nitrogen and sulphur is fused with sodium? Show Answer


Q459) In hyperconjugation, the atom involved is : Show Answer


Q460) Reactivity of hydrogen atoms attached to different atoms in alkanes has the order : Show Answer


Q461) Which has maximum percentage of chlorine? Show Answer


Q462) Which reaction sequence would be best to prepare 3-chloro-aniline from benzene? Show Answer


Q463) Why is light necessary to bring in chlorination reactions of alkane? Show Answer


Q464) For all practical purposes, influence of inductive effect is neglected after : Show Answer


Q465) Geometrical isomers differ in : Show Answer


Q466) The study of three dimensional structure of molecule is called : Show Answer


Q467) Which of the following contains only three pairs of electrons? Show Answer


Q468) 2-hexyne gives trans-2-hexene on treatment with Show Answer


Q469) Lassaigne’s test for the detection of nitrogen fails in Show Answer


Q470) The relative adsorption of each component of the mixture is expressed in terms of Show Answer


Q471) t-butyl alcohol is Show Answer


Q472) A compound containing 80% C and 20% H is likely to be Show Answer


Q473) Overlap of which of the following atomic orbitals would be maximum to form the strongest covalent bond? Show Answer


Q474) During elimination reactions, the hybrid state of carbon atoms involved in change shows: Show Answer


Q475) Who proposed the tetrahedral mirror image structures to a pair of enantiomers? Show Answer


Q476) Heterolysis of propane gives : Show Answer


Q477) Delocalised electrons are present in Show Answer


Q478) Compounds which rotate plane polarised light in clockwise direction are known as : Show Answer


Q479) Carbanions initiate : Show Answer


Q480) Impure glycerine can be purified by Show Answer


Q481) IUPAC name of urea is : Show Answer


Q482) Which of the following process is not used for the purification of solid impurities? Show Answer


Q483) Dehydration of alcohol is an example of which type of reaction? Show Answer


Q484) The organic liquid that mix freely with water is : Show Answer


Q485) The best method for the separation of naphthalene and benzoic acid from their mixture is Show Answer


Q486) The reagent used in dehydrohalogenation process is : Show Answer


Q487) Hydride shift from C-2 will give the most stable resonance stabilized carbocation as Show Answer


Q488) Hyperconjugation involves overlap of the following orbitals Show Answer


Q489) Most stable carbonium ion is Show Answer


Q490) During a nitration of benzene, the attacking electrophile is Show Answer


Q491) The (R) and (S) enantiomers of an optically active compound differ in Show Answer


Q492) The number of chiral centres in (+) –glucose Show Answer


Q493) Hydrogen cyanide and hydrogen isocyanide are : Show Answer


Q494) Which of the following hydrocarbons is most unsaturated? Show Answer


Q495) Sometimes the behaviour of a compound is explained by assuming that it exists in a world between two or
more different possible structures. This phenomenon is called : Show Answer


Q496) Which one of the following pairs represents stereoisomerism? Show Answer


Q497) The large number of organic compounds is due to: Show Answer


Q498) Formic acid is a stronger acid than acetic acid. This can be explained using Show Answer


Q499) The energy of C— C triple bond in acetylene in kcal is : Show Answer


Q500) In which of the following molecules, the resonance effect is not present? Show Answer


Q501) The tautomeric form which is less stable is called : Show Answer


Q502) The effect involving the complete transfer of a shared pair of electrons to one of the atoms joined by a
multiple bond at the requirement of attacking reagent is called : Show Answer


Q503) Which of the following acids does not exhibit optical isomerism? Show Answer


Q504) Which of the following conformations of cyclohexane is chiral? Show Answer


Q505) Which type of isomerism is shown by propanal and propanone? Show Answer


Q506) The best method to separate the mixture of ortho -and-para nitrophenol (1:1) is Show Answer


Q507) Which of the following does not show electrometric effect? Show Answer


Q508) Shifting of electrons of a multiple bond under the influence of a reagent is called : Show Answer


Q509) 0.4 g of a silver salt of a monobasic orgainc acid gave 0.26 g pure silver on ignition. the molecular weight of
the acid is (atomic weight of silver=108) Show Answer


Q510) Which pair represents chain isomers? Show Answer


Q511) The number of valence electrons in the excited carbon atom is : Show Answer


Q512) A hydrocarbon contains 10.5 g carbon and 1 g hydrogen. Its 2.4 g has 1 L volume at 1 atm and127℃.
Hydrocarbon is Show Answer


Q513) A mixture of oil and water is separated by Show Answer


Q514) The structural formula of methyl aminomethane is : Show Answer


Q515) The number of optically active isomers of tartaric acid are Show Answer


Q516) Which of the following has the highest degree of coordination bond? Show Answer


Q517) A mixture of o-nitrophenol and p-nitrophenol can be separated by Show Answer


Q518) State the hybridization of carbon present in triplet carbene Show Answer


Q519) Which of the following cannot show electromeric effect ? Show Answer


Q520) Hydride ion transfer takes place in Show Answer


Q521) An organic compound contains 29.27% carbon, 5.69 % hydrogen and 65.04% bromine. Its empirical
formula is Show Answer


Q522) The function of soda lime, a mixture of solid NaOH and solid CaO during decarboxylation of carboxylic
acids is : Show Answer


Q523) A racemic mixture is a mixture of : Show Answer


Q524) A mixture of iodine and sodium chloride can be easily separated by Show Answer


Q525) The property by virtue of which a compound can turn the plane of polarization of light is known as : Show Answer


Q526) Correct order of stability is Show Answer


Q527) In the estimation of sulphur in an organic compound, fuming nitric acid is used to convert sulphur into Show Answer


Q528) Which of the following will be chiral? Show Answer


Q529) Which of the following is not a nucleophile? Show Answer


Q530) Least stable conformer of cyclohexane is Show Answer


Q531) The compound isomeric with acetone is : Show Answer


Q532) Which of the chloride is less reactive towards hydrolysis? Show Answer


Q533) Glycerol is an alcohol which can be classified as Show Answer


Q534) The electromeric effect in organic compounds is a : Show Answer


Q535) Copper wire test of halogens is known as Show Answer


Q536) Which of the following is singlet carbine? Show Answer


Q537) Which of the following will be easily nitrated? Show Answer


Q538) Optical isomerism is shown by Show Answer


Q539) Williamson’s synthesis involves Show Answer


Q540) Free radicals can undergo : Show Answer


Q541) Metamers of ethyl propionate are Show Answer


Q542) During addition of bromine on ethene, the first species formed is Show Answer


Q543) Which one is not is IUPAC system? Show Answer


Q544) The compound which exhibits optical isomerism is : Show Answer


Q545) Homologous compounds have : Show Answer


Q546) How many chiral compound are possible on mono chlorination of 2-methyl butane? Show Answer


Q547) Which of the following IUPAC names is correct? Show Answer


Q548) Ethyl acetoacetate shows, which type of isomerism? Show Answer


Q549) Enol content is highest in Show Answer


Q550) The maximum number of stereoisomers possible for 3-hydroxy-2-methyl butanoic acid is : Show Answer


Q551) Which of the following will exhibit cis - trans isomerism? Show Answer


Q552) Which of the following is most reactive towards electrophilic nitration? Show Answer


Q553) Ethylene dichloride and ethylidine chloride are isomeric compounds. The false statement about these
isomers is that they Show Answer


Q554) Which of the following compounds has incorrect IUPAC nomenclature? Show Answer


Q555) The IUPAC name for tertiary butyl iodide is Show Answer


Q556) Geometry of methyl free radical is Show Answer


Q557) Dehydrogenation of ethanol to give ethanal is : Show Answer


Q558) Which one of the following compounds will be most readily dehydrated ? Show Answer


Q559) Among the following compounds (I-III) the correct order of reaction with the electrophile is Show Answer


Q560) Which of the following is an electrophile? Show Answer


Q561) An organic compound having carbon, hydrogen and sulphur contains 4% of sulphur. The minimum
molecular weight of the compound is Show Answer


Q562) The structure of tertiary butyl carbonium ion is : Show Answer


Q563) A carbonium ion contains : Show Answer


Q564) The formula of 3-chloro-2,2-dimethylbutane is : Show Answer


Q565) Which shows the easier electrophilic substitution in ring? Show Answer


Q566) The number of isomeric pentyl alcohols possible is Show Answer


Q567) Naphthalene can be easily purified by Show Answer


Q568) The correct structure of dimethylbutyne is : Show Answer


Q569) Which of the following is free radical? Show Answer


Q570) Quantitative measurement of nitrogen in an organic compound is done by the method Show Answer


Q571) During pyrolysis of an alkane, C— C bond breaks faster than the C— H bond because : Show Answer


Q572) State of hybridization of carbon atom of carbene in the singlet state is : Show Answer


Q573) The number of 1° and 2°carbon atoms in n-pentane are respectively : Show Answer


Q574) In benzene, all the C - C bonds are of equal length because of : Show Answer


Q575) Nitration of benzene is Show Answer


Q576) Nitrogen containing organic compound when fused with sodium forms Show Answer


Q577) Which of the following is strongest nucleophile? Show Answer


Q578) In Kjeldahl's method for the estimation of nitrogen, the formula used to Show Answer


Q579) The most satisfactory method to separate sugars is to use Show Answer


Q580) The structures that do not actually exist are called : Show Answer


Q581) Which of the following is the most stable carbocation? Show Answer


Q582) Which one of the following compound is most acidic? Show Answer


Q583) The number of carbon atoms present in neopentane are : Show Answer


Q584) The Cl—C—Cl angle in 1,1,2,2-tetrachloroethene and tetrachloromethane respectively will be about : Show Answer


Q585) The number of possible enantiomeric pairs that can be produced during monochlorination of 2-methyl
butane is : Show Answer


Q586) Chromatography technique is used for the separation of Show Answer


Q587) The stability of the carbocation decreases in the order Show Answer


Q588) What will be the compound if two valencies of carbonyl group are satisfied by two alkyl groups? Show Answer


Q589) The most stable carbocation is : Show Answer


Q590) Which of the following belongs to – I group? Show Answer


Q591) Which is most commonly used to dry organic liquids? Show Answer


Q592) In Lassaigne's solution, pink/violet colouration is produced when sodium nitroprusside solution is added.
It indicates the presence of Show Answer


Q593) A carbonium ion is formed when a covalent bond between two atoms in an organic compound undergoes : Show Answer


Q594) Racemic mixture is formed by mixing two Show Answer


Q595) In a solution, solvent can be separated from solute by one of the following process Show Answer


Q596) Buta-1,3-diene and But-2-yne are : Show Answer


Q597) The intermediate during the addition of HCl to propene in the presence of peroxide is : Show Answer


Q598) Which of the following represents neo- pentyl alcohol? Show Answer


Q599) 2-methyl-2-butene will be represented as : Show Answer


Q600) The most abundant organic compound in the world is : Show Answer


Q601) The chain initiating species in free radical chlorination of methane is : Show Answer


Q602) Which of the following belongs to +I group? Show Answer


Q603) Different structures generated due to rotation about, C – C axis, of an organic molecule, are examples of Show Answer


Q604) Which of the following molecules is expected to rotate the plane of plane-polarised light? Show Answer


Q605) Chromatography was discovered by Show Answer


Q606) Sodium nitroprusside when added to an alkaline solution of sulphide ions produces a colouration Show Answer


Q607) Isopentane can form four isomeric mono bromo derivatives. How many of them are optically active? Show Answer


Q608) Which one of the following does not show resonance? Show Answer


Q609) Select the organic compounds aliphatic in nature but burn with smoky flame : Show Answer


Q610) Which of the following is an electrophilic reagent? Show Answer


Q611) A mixture of iron fillings and sulphur cannot be separated by Show Answer


Q612) Isomers of propionic acid are Show Answer


Q613) Reactions involving heterolytic fission are said to proceed via : Show Answer


Q614) Which of the following orders is true regarding the acidic nature of COOH? Show Answer


Q615) Which behaves both as a nucleophile as well as an electrophile? Show Answer


Q616) In which case the carbon-carbon bond length is same? Show Answer


Q617) Incorrect statement is Show Answer


Q618) Which one of the following explain, why propene undergo electrophilic addition with HBr, but not with
HCN? Show Answer


Q619) Select the correct statement about the detection of sulphur in organic compounds Show Answer


Q620) Rotation of plane polarized light can be measured by : Show Answer


Q621) A molecule having three different chiral carbon atoms, how many stereoisomers it will have? Show Answer


Q622) Which of the following is the strongest base? Show Answer


Q623)
Intermediate product formed in the acid catalysed dehydration of n-propyl alcohol is : Show Answer


Q624) Which of the following has the highest nucleophilicity? Show Answer


Q625) Anthracene is purified by Show Answer


Q626) Chiral molecules are those which: Show Answer


Q627) Who is called the ‘Father of Chemistry’? Show Answer


Q628) With a change in hybridization of the carbon bearing the charge, the stability of a carbanion increase in the
order Show Answer


Q629) The total number of alkenes possible by dehydromination of 3-bromo-3-cyclopentylhexane using alcoholic
KOH is Show Answer


Q630) The Cl—C—Cl bond angle in dichloro methane will be : Show Answer


Q631) In the following reaction sequence, the chain initiation steps is : Show Answer


Q632) The most stable carbanion is Show Answer


Q633) If a compound on analysis was found to contain C = 18.5%, H = 1.55%, Cl =55.04% and O = 24.81% then
its empirical formula is Show Answer


Q634) 2-pentanone and 3-methyl-2-butanone are a pair of ….. isomers. Show Answer


Q635) Liebig’s test is used to estimate Show Answer


Q636) In fructose, the possible optical isomers are Show Answer


Q637) Which structure can be explained by taking ground state configuration of atom? Show Answer


Q638) Which one of the following carbanions is the least stable? Show Answer


Q639) Which one of the following is the most energetic conformation of cyclohexane? Show Answer


Q640) The energy difference between the chair and boat form of cyclohexane is : Show Answer


Q641) Addition of HI on double bond of propene yields isopropyl iodide as major product. It is because the
addition proceeds through : Show Answer


Q642) The IUPAC name of neopentane is : Show Answer


Q643) In Carius method of 0.099 g orgainc compound gave 0.287 g AgCl. The percentage of chlorine in the
compound will be Show Answer


Q644) The most common type of reaction in aromatic compounds is Show Answer


Q645) Arrange the following carbocations in order of stability
benzyl allyl methyl vinyl
I II III IV Show Answer


Q646) The prefix name of —SH group in IUPAC system is : Show Answer


Q647) Fractional distillation is a process by which the separation of different fractions from mixture of solution is
carried by making use of the following property of the fractions Show Answer


Q648) Which of the following is an electroplile? Show Answer


Q649) Which of the following is singlet carbine? Show Answer


Q650) Which of the following is the correct order of priority of groups in D-glyceraldehyde? Show Answer


Q651) o-hydroxytoluene and benzyl alcohol are : Show Answer


Q652) Which of the following would react most readily with nucleophiles? Show Answer


Q653) Which group has the highest + Inductive effect? Show Answer


Q654) The Prussian blue colour obtained during the test of nitrogen by Lassaigne;s test is due to the formation of Show Answer


Q655) Which of the following statements is correct? Show Answer


Q656) Which of the following possesses an sp-hybridized carbon in its structure? Show Answer


Q657) Di-chloroacetic acid is a stronger acid than acetic acid.
This due to occurrence of Show Answer


Q658) In which of the following ways does the hydride ion tend to function? Show Answer


Q659) The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC
system of nomenclature is Show Answer


Q660) Which of the following statements is incorrect? Show Answer


Q661) For the purification, isolation and separation of organic compounds, the latest technique followed is Show Answer


Q662) Arrange p-toluidine (I) N,N-dimethyl-p- toluidine (II) p- nitroaniline (III) and aniline (IV) in order of
decreasing basicity Show Answer


Q663) The reagent showing addition on alkene against the Markownikoff’s rule of : Show Answer


Q664) Carbocation can undergo : Show Answer


Q665) Lactic acid is : Show Answer


Q666) Of the following compounds which will have a zero dipole moment? Show Answer


Q667) Isomerism exhibited by acetic acid and methyl formate is : Show Answer


Q668) In IUPAC suffix name of —COX is : Show Answer


Q669) Which one of the following compounds is most reactive towards nucleopilic addition? Show Answer


Q670) Which of the following is the most stable cation? Show Answer


Q671) Which of the following species is not electrophilic in nature? Show Answer


Q672) The Beilstein test for organic compound is used to detect Show Answer


Q673) Which of the following statements is not characteristic of free radical chain reaction? Show Answer


Q674) The presence of carbon in an organic compound is detected by heating it with Show Answer


Q675) Which one is an elimination reaction? Show Answer


Q676) Identify the compound that exhibits tautomerism Show Answer


Q677) Which of the following is an electrophile? Show Answer


Q678) The formula of ethanenitrile is : Show Answer


Q679) Which of the following acids shows stereoisomerism? Show Answer


Q680) Mark the incorrect statement in nitrogen Kjeldahl's method of estimation Show Answer


Q681) Which of the following orders is correct regarding the –I effect of the substituents? Show Answer


Q682) The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is Show Answer


Q683) Lactic acid in which a methyl group, a hydroxyl group, a carboxylic acid group and a hydrogen atom are
attached to a central carbon atom shows optical isomerism due to the molecular geometry at the : Show Answer


Q684) Which of the following process is suitable for the purification of aniline? Show Answer


Q685) Maleic and fumaric acids are : Show Answer


Q686) Which one is least reactive in a nucleophile substitution reaction? Show Answer


Q687) Number of tertiary carbon atoms in tertiary butyl alcohol is : Show Answer


Q688) The correct sequence of steps involved in the mechanism of Cannizzaro’s reaction is Show Answer


Q689) Propanol and propanone are Show Answer


Q690) Diastereomers can be separated by : Show Answer


Q691) Angle strain in cyclopropane is Show Answer


Q692) A mixture of acetone and methanol can be separated by Show Answer


Q693) The oxygen atom in phenol Show Answer


Q694) 2-methylpent-3-enoic acid shows : Show Answer


Q695) Pyridine is : Show Answer


Q696) The reason for the loss of optical activity of lactic acid when – OH group is changed by H is that Show Answer


Q697) Which of the following compounds exhibits rotamers? Show Answer


Q698) The correct order of nucleophilicity among the following is : Show Answer


Q699) Ammonia molecule is : Show Answer


Q700) 0.5 g of hydrocarbon gave 0.9 g water on combustion. The percentage of carbon hydrocarbon is Show Answer


Q701) Which one of the following is most reactive towards electrophilic attack? Show Answer


Q702) Identify, which of the below does not possess any element of symmetry? Show Answer


Q703) Geometrical isomerism is shown by : Show Answer


Q704) When thiourea is heated with metallic sodium, the compound which can't be formed is Show Answer


Q705) The racemisation of optically active compounds is driven by : Show Answer


Q706) The correct name for the following hydrocarbon is Show Answer


Q707) Which of the following is the most stable radical? Show Answer


Q708) The number of 4° carbon atoms in 2,2,4,4-tetramethylpentane : Show Answer


Q709) Inductive effect involves Show Answer


Q710) Compounds whose molecules are superimposable on their mirror images even though they contain
asymmetric carbon atoms or chiral centres are known as : Show Answer


Q711) Percentage of hydrogen is maximum in . Show Answer


Q712) Which of the following has most acidic hydrogen? Show Answer


Q713) Ease of abstraction of hydrogen is greater when attached to : Show Answer


Q714) Steam distillation is based on the fact that vaporisation of organic liquid takes place at Show Answer


Q715) The hybridization of central carbon atom in 1,2- propadiene (allene) is Show Answer


Q716) The kind of delocalisation involving sigma bond is called Show Answer


Q717) In the case of homologous series of alkanes, which one of the following statements is incorrect? Show Answer


Q718) Which of the following reagents will be fruitful for separating a mixture of nitrobenzene and aniline? Show Answer


Q719) The name formic acid was given for HCOOH because it was prepared from : Show Answer


Q720) 2, 3-dimethyl hexane contains ….. tertiary ….. secondary and ……primary carbon atmos, respectively Show Answer


Q721) Which one of the following is the correct formula for dichlorodiphenyltrichloro ethane? Show Answer


Q722) How many sigma and pi bonds are there in the molecule of di cyano ethane (CN - CH - CH - CN)? Show Answer


Q723) Out of the following, the alkene that exhibits optical isomerism is Show Answer


Q724) Carbanion can undergo : Show Answer


Q725) Percentage composition of an organic compound is as follows
C=10.06, H=0.84, Cl=89.10
Which of the following corresponds to its molecular formula if the vapour density is 60.0? Show Answer


Q726) Which of the following is most reactive towards nucleophilic substitution reaction? Show Answer


Q727) Which among the following statements is correct with respect to the optical isomers? Show Answer


Q728) Which of the following is most basic? Show Answer


Q729) Which of the following compounds is not chiral? Show Answer


Q730) What is the number of possible optical isomers in glucose? Show Answer


Q731) In which reaction addition takes place according to Markownikoff’s rule? Show Answer


Q732) Presence of halogen in organic compounds can be detected using Show Answer


Q733) The bond energy for catenation next to carbon is : Show Answer


Q734) The hydrolysis of alkyl halides by aqueous NaOH is best termed as : Show Answer


Q735) Which of the following compounds exhibit stereoisomerism? Show Answer


Q736) The + I.E(inductive effect) is shown by : Show Answer


Q737) In paper chromatography Show Answer


Q738) Which one of the following is not found in alkenes? Show Answer


Q739) Select the correct statement : Show Answer


Q740) A compound contains 2 dissimilar asymmetric carbon atoms. The number of optically active isomers is : Show Answer


Q741) The inductive effect Show Answer


Q742) If there is no rotation of plane polarised light by a compound in a specific solvent, though to be chiral, it
means that : Show Answer


Q743) Formation of ethylene from acetylene is an example of Show Answer


Q744) Which of the following is nucleophilic addition reaction? Show Answer


Q745) The reagent used in dehalogenation process is : Show Answer


Q746) Benzaldoxime exists in how many forms? Show Answer


Q747) Resonance arises due to the : Show Answer


Q748) Which one of the following pair represents stereoisomerism? Show Answer


Q749) Stereoisomerism is of two types, geometrical and
optical. Show Answer


Q750) Which of the following compounds is expected to be optically active? Show Answer


Q751) Which of the following is least reactive in a nucleophilic substitution reaction? Show Answer


Q752) During debromination of meso-dibromo-butane, the major compound formed is : Show Answer


Q753) What is the empirical formula of a compound having 40% carbon, 6.66% hydrogen and 53.34% oxygen? Show Answer


Q754) Which of the following can act as an nucleophile? Show Answer


Q755) In Lassaigne’s test, a blue colour is obtained if the organic compound contains nitrogen. The blue colour is
due to Show Answer


Q756) According to Gahn-Ingold-Prelog sequence rules, the correct order of priority for the given group is Show Answer


Q757) How many chiral isomers can be drawn from 2-bromo, 3-chloro butane? Show Answer


Q758) Glycerol can be separated from spent-lye in soap industry by Show Answer


Q759) Correct gradation of basic charactor Show Answer


Q760) An organic compound contains 49.3% carbon, 6.84% hydrogen and its vapour density is 73. Molecular
formula of compound is Show Answer


Q761) Vital force theory of the origin of organic compounds was discarded by : Show Answer


Q762) In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-Markownikoff
addition to alkenes because : Show Answer


Q763) One is oxidizing and the other is reducing Show Answer


Q764) Which of the following is the correct order of stability of different conformations of butane? Show Answer


Q765) Glucose and fructose are : Show Answer


Q766) Eelipsed and staggered forms of n-butane are called a pair of : Show Answer


Q767) Arrange the following in order of increasing dipole moment (I) Toluene (II)m-dichlorobenzene (III) o-
dichlorobenzene (IV) p-dichlorobenzene : Show Answer


Q768) In butane, which of the following forms has the lowest energy? Show Answer


Q769) Molecular mass of a volatile substances may be obtained by Show Answer


Q770) Which is not deflected by a non-uniform electrostatic field? Show Answer


Q771) Correct order of nucleophilicity is Show Answer


Q772) Due to the presence of an unpaired electron free radicals are Show Answer


Q773) Which of the following will have meso isomers also? Show Answer


Q774) The addition of HBr on butene-2 in presence of peroxide follow the: Show Answer


Q775) Which represents nucleophilic aromatic substitution reaction? Show Answer


Q776) Ethoxy ethane and methoxy propane are : Show Answer


Q777) Which of the following aromatic acid is most acidic? Show Answer


Q778) The hybridization of carbon in diamond, graphite and acetylene is in the order: Show Answer


Q779) Which is optically active? Show Answer


Q780) Which of the following statement is wrong? Show Answer


Q781) What kind of isomerism is possible for 1-chloro-2-nitroethene? Show Answer


Q782) Acetonitrile is Show Answer


Q783) Formation of cyanohydrin from a ketone is an example of Show Answer


Q784) An organic compound which produces a bluish green coloured flame on heating in presence of copper is Show Answer


Q785) The compound abd C—C abd will exist in : Show Answer


Q786) The C - H bond distance is longest in Show Answer


Q787) The yield in organic reactions is generally poor because the reactions are : Show Answer


Q788) Which of the following resonating structures of 1-methoxy-1, 3-butadiene is least stable? Show Answer


Q789) A student named the compound as 1,4-butadiene : Show Answer


Q790) The number of different substitution products possible when ethane is allowed to react with bromine is
sunlight are : Show Answer


Q791) Phenol is more acidic than Show Answer


Q792) During the fusion of an organic compound with sodium metal, nitrogen of the compound is converted into Show Answer


Q793) The structure representing a heterocyclic compound is : Show Answer


Q794) Which of the following reactions is an example of nucleophilic substitution reaction? Show Answer


Q795) In which of the following species the central carbon atom is negatively charged? Show Answer


Q796) Optically active compound among the following is : Show Answer


Q797) Which of the following compounds will be most reactive towards nucleophilic addition reaction? Show Answer


Q798) n-pentane and neopentane are : Show Answer


Q799) The IUPAC name of acryldehyde is Show Answer


Q800) Due to presence of an unpaired electron, free radicals are Show Answer


Q801) 2-methylpent-3-ene is a chiral because it has : Show Answer


Q802) Which of the following molecules contain asymmetric carbon atom? Show Answer


Q803) Cyclobutane and butene-1 are : Show Answer


Q804) Which of the following is not true for carbanions? Show Answer


Q805) Which of the following structures permits cis-trans isomerism? Show Answer


Q806) Which one of the following compound will show optical iosmerism? Show Answer


Q807) The Kolbe’s electrolysis proceeds via Show Answer


Q808) Which of the following statements is not correct? Show Answer


Q809) Adsorbent is made of ... in TLC Show Answer


Q810) The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen
was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20 mL of 0.5 M sodium
hydroxide solution for complete neutralization. the organic compound is Show Answer


Q811) The structure remaining after one H is removed from hydrocarbon is : Show Answer


Q812) Tautomerism is exhibited by Show Answer


Q813) Which of the following statements is incorrect? Show Answer


Q814) Base strength of, Show Answer


Q815) Which of the following Fischer’s projection formula is identical to D-glyceraldehyde? Show Answer


Q816) Among the following the dissociation constant is highest for Show Answer


Q817) Which of the following is a dynamic isomerism? Show Answer


Q818) Which among the following statements is correct with respect to the optical isomers? Show Answer


Q819) Duma's method involves the determination of nitrogen content in the organic compound in the form of Show Answer


Q820) n- pentane and 2-methyl butane are a pair of Show Answer


Q821) Amongst the following the compound that can most readily get sulphonated is Show Answer


Q822) In E2 elimination, some compounds follow Hofmann’s rule which means: Show Answer


Q823) How many asymmetric carbon atoms are present in
(i) 1, 2-dimethylcyclohexane
(ii) 3-methylcyclopentane and
(iii) 3-methylcyclohexene? Show Answer


Q824) Which of the following is a chiral compound? Show Answer


Q825) The maximum number of possible optical isomers in 1-bromo-2-methyl cyclobutane is Show Answer


Q826) Vinyl alcohol and acetaldehyde are : Show Answer


Q827) Stereoisomers (geometrical or opticals) which are neither superimposable nor mirror image to each other
are called : Show Answer


Q828) Which one of the following will show optical isomerism? Show Answer


Q829) Chloroacetic acid is a stronger acid than acetic acid. This can be explained using Show Answer


Q830) The basicity of aniline is less than that of cyclohexylamine. This is due to Show Answer


Q831) Dehydration of alcohol usually goes by Show Answer


Q832) Geometrical isomerism is possible in Show Answer


Q833) The maximum number of possible optical isomers in 1-bromo-2-methyl cyclobutane is Show Answer


Q834) Ethers are isomeric with Show Answer


Q835) Vinyl chloride undergoes Show Answer


Q836) Fischer projection indicates : Show Answer


Q837) Acetone and propen-2-ol are : Show Answer


Q838) The number of stereoisomers obtained by bromination of trans - 2 -butene is? Show Answer


Q839) The compound which forms one monochloro product when treated with chlorine is : Show Answer


Q840) Maleic acid and fumaric acid are Show Answer


Q841) Which represents the condensed formula for pentanes? Show Answer


Q842) Which of the substance is purified by sublimation? Show Answer


Q843) The halogen compound which most readily undergoes nucleophilic substitutions is Show Answer


Q844) Which of the following order is correct regarding the acidity of carboxylic acids? Show Answer


Q845) Reaction of methyl bromide with aqueous sodium hydroxide involves Show Answer


Q846) The following compound will undergo electrophilic substitution more readily than benzene Show Answer


Q847) Which of the following elements can't be detected by direct tests? Show Answer


Q848) Position isomerism is shown by : Show Answer


Q849) Formulae of phenyl carbinol and chloral are respectively : Show Answer


Q850) The reaction of sodium ethoxide with iodoethane to from diethyl is termed as Show Answer


Q851) The sodium extract of an organic compound on acidification with acetic acid and addition of lead acetate
solution gives a black precipitate. The organic compound contains Show Answer


Q852) The silver salt of a monobasic acid on ignition gave 60% of Ag. The molecular weight of the acid is Show Answer


Q853) The resonating structures : Show Answer


Q854) How many optically active stereoisomers are possible for butane-2, 3-diol? Show Answer


Q855) Removal of a hydride ion from a methane molecule will give a: Show Answer


Q856) Which of the following will have a meso-isomer also? Show Answer


Q857) Which chlorine atom is more electronegative in the following? Show Answer


Q858) The resonating structures : Show Answer


Q859) The optical isomers, which are not enantiomers, are called Show Answer


Q860) Which of the following orders is correct regarding the acidity of carboxylic group? Show Answer


Q861) Geometrical isomerism is shown by Show Answer


Q862) Which one of the following is s-butyl phynylvinyl methane? Show Answer


Q863) Bicyclo (1,1,0) butane is Show Answer


Q864) The reaction of sodium ethoxide with iodoethane to from diethyl is termed as Show Answer


Q865) Which of the following is most reactive towards elimination reaction? Show Answer


Q866) The number of isomeric hexanes is Show Answer


Q867) The substitution reaction among the following is Show Answer


Q868) The most stable carbocation is Show Answer


Q869) Which of the following statements is not correct? Show Answer


Q870) How many chiral carbon atoms are present in 2, 3, 4- trichloropentane? Show Answer


Q871) Which one of the following compounds is most polar? Show Answer


Q872) Geometrical isomerism is not shown by Show Answer


Q873) The change in optical rotation with time of freshly prepared solution of sugar is known as: Show Answer


Q874) Which of the following does not show stereo isomerism? Show Answer


Q875) One of the following compounds exhibit geometrical iosmerism Show Answer


Q876) Which one of the following shows functional isomerism? Show Answer


Q877) In the reaction of phenol with chloroform and aqueous solution of NaOH at 70°C, the electrophile attacking
the ring is Show Answer


Q878) The production of an optically active compound from a symmetric molecule without resolution in termed
as : Show Answer


Q879) Which of the following statement is not applicable to Beilstein test? Show Answer


Q880) Essential oils can be isolated by Show Answer


Q881) Mesomeric effect involves delocalisation of Show Answer


Q882) Which of the following species is paramagnetic in nature? Show Answer


Q883) Isobutyl chloride is : Show Answer


Q884) Which one of the following compounds is capable of existing in a meso form? Show Answer


Q885) Geometrical isomerism is caused : Show Answer


Q886) Lassaigne's test is used for the detection of Show Answer


Q887) Which of the following is arranged according to the nature indicated? Show Answer


Q888) Example of geometrical isomerism is Show Answer


Q889) Which of the following is an example of elimination reaction? Show Answer


Q890) Which nomenclature in IUPAC is not correct? Show Answer


Q891) The C—C bond angle in cyclopropane is : Show Answer


Q892) Absolute alcohol cannot be obtained by simple fractional distillation because Show Answer


Q893) Racemic compound has Show Answer


Q894) In case of a homologous series each member differs from the preceding or the succeeding member by : Show Answer


Q895) Vaccum distillation is used to purify liquids which Show Answer


Q896) Which of the following is the weakest base? Show Answer


Q897) The structure which has positive charge on the oxygen atom : Show Answer


Q898) Statement 1: Lessaigne's test is the for nitrogen only
Statement 2: If halogens are present in organic compound, it react with sodium to form sodium halides
which dissolves in water Show Answer


Q899) Statement 1: Benzoic acid is purified by sublimation process
Statement 2: Sublimation process is very useful in separating a volatile solid from a non-volatile solid Show Answer


Q900) Statement 1: The molality of the solution does not change with change in temperature.
Statement 2: The molality of the solution is expressed in units of moles per 1000 g of solvent. Show Answer


Q901) Statement 1: ‘A Victor Mayer tube’ of hard glass, having a side-tube, leading to the arrangement for
collection of displaced air over water.
Statement 2: An outer jacket of copper, containing a liquid boiling at nearly 30℃ higher than the
substance whose molecular mass is to be determined Show Answer


Q902) Statement 1: Normally and molarity can be calculated from each other.
Statement 2: Normally is equal to the product of molarity and n. Show Answer


Q903) Statement 1: Carbanion like ammonia have pyramidal shape
Statement 2: The carbon atom carrying negative charge has an octet of electrons Show Answer